Top 5 ways to learn another language.

FSI
http://www.fsi-language-courses.com/

Free Education List (podcasts)
http://www.eliteskills.com/free_education/
http://podcasts.yahoo.com/
http://www.podcastalley.com/

LiveMocha
http://livemocha.com/

TryMango
http://www.trymango.com/

Wikibooks
http://en.wikibooks.org/wiki/Category:Languages

Guutenberg Audio Books
http://www.gutenberg.org/wiki/Gutenberg:The_Audio_Books_Project

LibriVox (select flag on right)
http://librivox.org/

User Posted Suggestions:

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My fav chinese tv series